NANOTECHNOLOGY

NANOTECHNOLOGY
1 YEAR II semester  6 CFU
Antonio Agresti (3cfu)
Francesca De Rossi (3cfu)
A.Y. 2021-22
Antonio Agresti (3cfu)
Fabio Matteocci (3cfu)
A.Y. 2022-23
A.Y. 2023-24
Antonio Agresti A.Y. 2024-25
Code: 8039791
SSD: ING-INF/01

(to be updated for A.A. 24-25)

LEARNING OBJECTIVES AND EXPECTED LEARNING OUTCOMES:

LEARNING OUTCOMES:
The first part of the Nanotechnology course introduces thin film depositions using both physical and chemical vapour depositions. The main objective is the knowledge of the potential and limits of the different thin film depositions in the nanotechnology field. Particular attention is destinated to the deposition technique used in micro and nanoelectronics based on semiconductors using top-down and bottom-up approaches. The interaction of both approaches has been discussed with the student in order to share the importance of multidisciplinary knowledge (physics, chemistry and engineering) where the nanotechnology field is based. The final part of module 1 is destinated to the introduction of the case study of the course about the thin film fabrication of an emergent photovoltaic technology: the perovskite solar cells. In particular, the study of the optoelectronic properties of the materials and the fabrication of several device architectures is important to understand the important role of the manufacturing design in thin film photovoltaic technologies destinated at the industrial level.

KNOWLEDGE AND UNDERSTANDING:
Regarding the first module, at the end of the course, the student will have a clear overview of the main deposition technique studied and applied in nanotechnology for different application fields.
Regarding the second module, at the end of the course, the student will know the main characterization techniques for nanostructured materials and electronic and optoelectronic devices till nanometric size.

APPLYING KNOWLEDGE AND UNDERSTANDING:
The student will be able to recognize the applicability areas for the various characterization and realization techniques at nanometric scales. She/He will also be able to apply the knowledge and understanding developed during the course to study and understand recent literature.

MAKING JUDGEMENTS:
The transversal preparation provided by the course implies
1) the student’s capability to integrate knowledge and manage complexity
2) the student’s ability to deal with new and emerging areas in nanotechnology application to energy and nanoelectronics.

COMMUNICATION SKILLS:
The student will be able to clearly and unequivocally communicate the course content to specialized interlocutors. He will also be able to communicate the main physico-chemical characteristics of nanostructured materials and to indicate the most appropriate deposition/processing technique of these materials to technical interlocutors (example: other engineers, physicists, chemists) but not specialists in the field of electronics or devices. The student will also have a sufficient background to undertake a thesis/research work in modern nanotechnology laboratories.

LEARNING SKILLS:
The structure of the course contents, characterized by various topics apparently separated but connected by an interdisciplinary and modular vision, will contribute to developing a systemic learning capacity that will allow the student to approach in a self-directed or autonomous way to other frontier problems on nanotechnology application to energy and nanoelectronics. Furthermore, the student will be able to read and understand recent scientific literature.

 

SYLLABUS

 

First Module: 1 Prof. Antonio Agresti (3 cfu)

1) Quantum Mechanics and p-n junction

2 )Solar Cells: main electrical characterization techniques

3) Absorbance and Fluorescence Spectroscopy

4) Electron scanning microscopy (SEM)

5) Electron transmission microscopy (TEM)

6) Scanning tunneling microscopy (STM)

7) Atomic force microscopy (AFM)

8) Kelvin Probe Microscopy (KPFM)

9) Raman spectroscopy

10) Bi-Dimensional Materials

 

Second module – Prof. Fabio Matteocci (3cfu)

 

1) Introduction to nanotechnology and thin film properties;
2) Thin Film Deposition: the importance of vacuum and plasma;
3) Thermal Evaporation: Working mechanism, material properties, deposition parameters and applications;
4) DC and RF Sputtering: Working mechanism, material properties, deposition parameters and applications;
5) Pulsed Laser Deposition: Working mechanism, material properties, deposition parameters and applications;
6) Chemical Vapour Deposition: Working mechanism, material properties, deposition parameters and applications;
7) Atomic Layer Deposition: Working mechanism, material properties, deposition parameters and applications;
8) Solution Processing: Spin coating, Screen Printing, Blade Coating, Slot die coating;
9) Patterning Procedures: Photolithography and Laser Ablation;
10) Introduction to Perovskite Solar Cell: Working mechanism, material properties, deposition techniques, up-scaling process and applications;
11) Building Integration Photovoltaics;

Feedback Control Systems (block B)

Feedback Control Systems (block B)
1 YEAR II semester  6 CFU
Cristiano M. VERRELLI A.Y. 2021-22
A.Y. 2022-23
Code:
SSD: ING-INF/04

FORMATIVE OBJECTIVES

LEARNING OUTCOMES:

The theory of differential equations is successfully used to gain profound insight into the fundamental mathematical control design techniques for linear and nonlinear dynamical systems.

KNOWLEDGE AND UNDERSTANDING:

Students should be able to deeply understand (and be able to use) the theory of differential equations and of systems theory, along with related mathematical control techniques.

APPLYING KNOWLEDGE AND UNDERSTANDING:

Students should be able to design feedback controllers for linear (and even nonlinear) dynamical systems.

MAKING JUDGEMENTS:

Students should be able to identify the specific design scenario and to apply the most suitable techniques. Students should be able to compare the effectiveness of different controls while analyzing theoretical/experimental advantages and drawbacks.

COMMUNICATION SKILLS: Students are expected to be able to read and capture the main results of a technical paper concerning the topics of the course, as well as to effectively communicate in a precise and clear way the content of the course. Tutor-guided individual projects (including Maple and Matlab-Simulink computer simulations as well as visits to labs) invite intensive participation and ideas exchange.

LEARNING SKILLS:

Being enough skilled in the specific field to undertake the following studies characterized by a high degree of autonomy.

SYLLABUS:

The matrix exponential; the variation of constants formula.

Computation of the matrix exponential via eigenvalues and eigenvectors and via residual matrices. Necessary and sufficient conditions for exponential stability: Routh-Hurwitz criterion. Invariant subspaces.

Impulse responses, step responses and steady state responses to sinusoidal inputs. Transient behaviours. Modal analysis: mode excitation by initial conditions and by impulsive inputs; modal observability from output measurements; modes which are both excitable and observable. Popov conditions for modal excitability and observability. Autoregressive moving average (ARMA) models and transfer functions.

Kalman reachability conditions, gramian reachability matrices and the computation of input signals to drive the system between two given states. Kalman observability conditions, gramian observability matrices and the computation of initial conditions given input and output signals. Equivalence between Kalman and Popov conditions.

Kalman decomposition for non-reachable and non-observable systems.

Eigenvalues assignment by state feedback for reachable systems. Design of asymptotic observers and Kalman filters for state estimation of observable systems. Design of dynamic compensators to stabilize any reachable and observable system. Design of regulators to reject disturbances generated by linear exosystems.

Bode plots. Static gain, system gain and high-frequency gain.

Zero-pole cancellation.

STATISTICS:

A.Y.  Mechatronics students Other courses Students Mechatronics average Other courses average
2019/2020 10 62 24 23
2020/2021 19 25 23 24
2021/2022 13 44 21 22

Innovative Materials with Laboratory (blocks B-C-C1-E)

Innovative Materials with Laboratory (blocks B-C-C1-E)
1 YEAR 1 semester 6 CFU
TATA MARIA ELISA (1cfu)
COSTANZA GIROLAMO (1cfu)
VARONE ALESSANDRA (4cfu)
A.Y. 2021-22
A.Y. 2022-23
A.Y. 2023-24 (MS TEAMS)
A.Y. 2024-25 (C1-E)
Code: 8039786
SSD: ING-IND/21

LEARNING OUTCOMES:
The aim of the course is to provide an overview of novel materials recently developed and investigated for applications in mechanics, electronics, and mechatronics. Different types of materials are considered and described with particular attention on the preparation route, specific characteristics, and applications. Some of them are of basic importance for new technologies gaining increasing attention in industrial practice. The knowledge of innovative materials is strictly connected to the possibility and capability of designing new products.

KNOWLEDGE AND UNDERSTANDING:
Deep knowledge of the metallic structure and their mechanical behavior; in particular knowledge of innovative materials for mechatronics applications; selection of conventional material or not as a function of application, structure and properties.

APPLYING KNOWLEDGE AND UNDERSTANDING:
Ability to define materials properties and the most suitable production technologies for the components realization; Ability to perform tests in laboratory; Ability to define appropriate treatments in order to obtain the suitable mechanical properties as a function of service conditions. Ability to select innovative materials; ability to evaluate innovative materials properties.

MAKING JUDGEMENTS:
Ability to investigate, select and choose metallic materials as a function of the application.

COMMUNICATION SKILLS:
Clear and correct expression, in English language, skills on the topics covered in the course.

LEARNING SKILLS:

Ability to face a new problem, know how to manage it and find functional and correct solutions. learning ability will be evaluated by exam tests and laboratory activities.

SYLLABUS:

Metallurgy Fundamentals: crystal structure, defects, plastic deformation. Mechanical tests.

Amorphous alloys: production and applications of metallic glasses as mechatronic devices. Alloys with mixed structure (nanocrystalline and amorphous).

Ultrafine grained (UFG) materials: microstructural features and production routes.

Nanoporous and mesoporous materials: structural characterization and properties. Their applications for energy and gas storage.

Powder metallurgy, Additive Manufacturing Technologies.

Advanced composite materials: properties, applications and production routes.

Porous materials: metal foams, Open and closed porosity (micro and macro). Classification according to size and shape of the pores. Properties (sound, energy and vibration absorption, crash

behavior) and production methods. Functional and structural

applications: lightweight construction, automotive. Metal sandwich structures.

Functional and Smart Materials. Property change as a response of external stimulus: shape memory alloy (one-way and two-way shape memory), thermochromic, photomechanical. Energy conversion: piezoelectric, thermoelectric. Phase change materials. 

Applications: mechatronic, energy. Functionally graded materials.